Hysteretic Three‐Step Spin Crossover in a Thermo‐ and Photochromic 3D Pillared Hofmann‐type Metal–Organic Framework
Identifieur interne : 005666 ( Main/Exploration ); précédent : 005665; suivant : 005667Hysteretic Three‐Step Spin Crossover in a Thermo‐ and Photochromic 3D Pillared Hofmann‐type Metal–Organic Framework
Auteurs : Natasha F. Sciortino [Australie] ; Katrin R. Scherl-Gruenwald [Australie] ; Guillaume Chastanet [France] ; Gregory J. Halder [États-Unis] ; Karena W. Chapman [États-Unis] ; Jean-François Létard [France] ; Cameron J. Kepert [Australie]Source :
- Angewandte Chemie [ 0044-8249 ] ; 2012-10-01.
English descriptors
- KwdEn :
- Angew, Angewandte zuschriften figure, Bond lengths, Bousseksou, Brief existence, Chem, Crossover, Crossover behavior, Dalton trans, Dpsme, Dpsme pillars, Financial support, Halder, Host framework, Hysteresis, Intermediate phases, Intermediate states, Kepert, Lattice, Lattice states, Magnetic data, Mater, Material exhibits tristability, Modulation peaks, Moubaraki, Neville, Pillared topology, Progressive decrease, Room temperature, Thermal dependence, Thermal hysteresis, Verlag gmbh.
- Teeft :
- Angew, Angewandte zuschriften figure, Bond lengths, Bousseksou, Brief existence, Chem, Crossover, Crossover behavior, Dalton trans, Dpsme, Dpsme pillars, Financial support, Halder, Host framework, Hysteresis, Intermediate phases, Intermediate states, Kepert, Lattice, Lattice states, Magnetic data, Mater, Material exhibits tristability, Modulation peaks, Moubaraki, Neville, Pillared topology, Progressive decrease, Room temperature, Thermal dependence, Thermal hysteresis, Verlag gmbh.
Abstract
Multistabilität wird bei einem Metall‐organischen Gerüstmaterial beobachtet, das einen einzigartigen dreistufigen Spin‐Crossover mit einer thermischen Hysterese von 20 K eingeht (siehe Bild). Der stufenweise Übergang ist mit einer dreistufigen Strukturänderung gekoppelt, die vier spezifische Strukturzustände definiert. Das Material zeigt außerdem einen reversiblen photoinduzierten Spin‐Crossover.
Url:
DOI: 10.1002/ange.201204387
Affiliations:
- Australie, France, États-Unis
- Aquitaine, Nouvelle-Aquitaine, Nouvelle-Galles du Sud
- Bordeaux, Sydney
- Université Bordeaux I, Université de Sydney
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Le document en format XML
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Der stufenweise Übergang ist mit einer dreistufigen Strukturänderung gekoppelt, die vier spezifische Strukturzustände definiert. Das Material zeigt außerdem einen reversiblen photoinduzierten Spin‐Crossover.</div></front></TEI><affiliations><list><country><li>Australie</li><li>France</li><li>États-Unis</li></country><region><li>Aquitaine</li><li>Nouvelle-Aquitaine</li><li>Nouvelle-Galles du Sud</li></region><settlement><li>Bordeaux</li><li>Sydney</li></settlement><orgName><li>Université Bordeaux I</li><li>Université de Sydney</li></orgName></list><tree><country name="Australie"><region name="Nouvelle-Galles du Sud"><name sortKey="Sciortino, Natasha F" sort="Sciortino, Natasha F" uniqKey="Sciortino N" first="Natasha F." last="Sciortino">Natasha F. Sciortino</name></region><name sortKey="Kepert, Cameron J" sort="Kepert, Cameron J" uniqKey="Kepert C" first="Cameron J." last="Kepert">Cameron J. Kepert</name><name sortKey="Kepert, Cameron J" sort="Kepert, Cameron J" uniqKey="Kepert C" first="Cameron J." last="Kepert">Cameron J. Kepert</name><name sortKey="Kepert, Cameron J" sort="Kepert, Cameron J" uniqKey="Kepert C" first="Cameron J." last="Kepert">Cameron J. Kepert</name><name sortKey="Scherl Ruenwald, Katrin R" sort="Scherl Ruenwald, Katrin R" uniqKey="Scherl Ruenwald K" first="Katrin R." last="Scherl-Gruenwald">Katrin R. Scherl-Gruenwald</name></country><country name="France"><region name="Nouvelle-Aquitaine"><name sortKey="Chastanet, Guillaume" sort="Chastanet, Guillaume" uniqKey="Chastanet G" first="Guillaume" last="Chastanet">Guillaume Chastanet</name></region><name sortKey="Letard, Jean Rancois" sort="Letard, Jean Rancois" uniqKey="Letard J" first="Jean-François" last="Létard">Jean-François Létard</name></country><country name="États-Unis"><noRegion><name sortKey="Halder, Gregory J" sort="Halder, Gregory J" uniqKey="Halder G" first="Gregory J." last="Halder">Gregory J. Halder</name></noRegion><name sortKey="Chapman, Karena W" sort="Chapman, Karena W" uniqKey="Chapman K" first="Karena W." last="Chapman">Karena W. Chapman</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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